The many NCC Officers at St. Paul’s have ensured that the school chapter lives up to the name of the glorious institution that it is, and this can be clearly seen by the number of NCC achievers at the national level, where St. Paul’s features among the top few institutions. To top it all, in the years 2014-2015 and 2016-2017, St. Paul’s has been selected as the “Best Institution – Junior Division (Boys) – Karnataka and Goa Directorate”. In the past too, during the initial days of ACC, ie the predecessor to NCC, St. Paul’s was awarded with the prize for “Best ACC Group, Belgaum” in 1957 and 1958.
| NCC Roll of Honour | |||||
| Year | Cadet | Achievement | Year | Cadet | Achievement |
| 1995 | Cdt Brian D’Souza | BLC | 2008 | Cdt Harshwardhan Rawoot (All India Best Cadet Silver Medal) |
RDC |
| 1997 | Cdt Sameer Sanadi | RDC | 2008 | Cdt Prakash Sharma | TSC |
| 1998 | Cdt Indrakumar Hongekar | RDC | 2008 | Cdt Utkarsh Mangale | TSC |
| 1999 | Cdt Abhishek Deshpande | RDC | 2008 | Cdt Divij Mahajan | RDC |
| 2000 | Cdt Alhad Patil (All India Best Cadet Gold Medal) |
RDC | 2008 | Cdt Ashish Mahendrakar | RDC |
| 2001 | Cdt Rasad Angolkar | TSC | 2008 | Cdt Akash Angadi | RDC |
| 2001 | Cdt Julian Correa | RDC | 2009 | Cdt Rajat Hardi | RDC |
| 2001 | Cdt Rahul Dumavat | TSC | 2009 | Cdt Jayesh Patil | TSC |
| 2002 | Cdt Vishwas Gawade | TSC | 2011 | Cdt Sanath Prakash Patil | RDC |
| 2003 | Cdt Aiyanna | TSC | 2011 | Cdt Rahul Rudragouda | RDC |
| 2003 | Cdt Aniket Deshpande | RDC | 2014 | Cdt Vaibhav Pai (All India Best Cadet Silver Medal) |
RDC |
| 2004 | Cdt Vaibhav Manjrekar (All India Best Cadet Gold Medal) |
RDC | 2014 | Cdt Akash Patil | RDC |
| 2004 | Cdt Amit Choudhari | RDC | 2015 | Cdt Makrand Halgekar | RDC |
| 2004 | Cdt Ravi Patil | TSC | 2016 | Cdt Sriram Baliga | |
| 2005 | Cdt Yassar Hafiz | TSC | 2016 | Cdt Hardeek Khorvi | RDC |
| 2005 | Cdt Santan Rodrigues | TSC | 2016 | Cdt Ninad Halgekar (All India Best Cadet Gold Medal) |
RDC |
| 2005 | Cdt Siddharth Shenvi (All India Best Cadet Bronze Medal) |
RDC | 2017 | Ctd Joy Monteiro | RDC |
| 2005 | Cdt Sagar Dhond | RDC | 2019 | Ctd Vishwanath S Ankalgi (Army) | RDC |
| 2006 | Cdt Joel Paul | RDC | 2019 | Ctd Sgt Veerkumar R Karlingannavar (Air) | RDC |
| 2007 | Cdt Shivraj Patil | RDC | 2019 | Ctd Sgt Praneet V Kalyanshetti (Air) (All India Best Cadet Silver Medal) |
RDC |
| 2007 | Cdt Aditya Vaigankar | RDC | 2020 | Ctd Cpl Viraj M Kulkarni (Air) | RDC |
| 2007 | Cdt Zain Ternikar | RDC | |||
| BLC – Basic Leadership Camp; RDC – Republic Day Camp; TSC – Thal Sainik Camp | |||||